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Dutta, Suryendu
- Pyrolytic and Spectroscopic Studies of Eocene Resin from Vastan Lignite Mine, Cambay Basin, Western India
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1 Department of Earth Sciences, Indian Institute of Technology-Bombay, Powai, Mumbai - 400 076, IN
2 WA Biogeochemistry and John de Laeter Mass Spectrometry Centres, University of Western Australia, 35 Stirling Hwy, Crawley 6009, AU
3 LTA-Labor fuer Toxikologie und Analytik, Friedrichshoeher Str. 28, D-53639 Koenigswinter, DE
1 Department of Earth Sciences, Indian Institute of Technology-Bombay, Powai, Mumbai - 400 076, IN
2 WA Biogeochemistry and John de Laeter Mass Spectrometry Centres, University of Western Australia, 35 Stirling Hwy, Crawley 6009, AU
3 LTA-Labor fuer Toxikologie und Analytik, Friedrichshoeher Str. 28, D-53639 Koenigswinter, DE
Source
Journal of Geological Society of India (Online archive from Vol 1 to Vol 78), Vol 74, No 1 (2009), Pagination: 16-22Abstract
The molecular structure of an Eocene fossil resin (Vastan, Cambay basin, Western India) has been investigated with complimentary spectroscopic techniques. The FTIR spectrum shows strong aliphatic CHx (3000-2800 and 1460- 1450 cm-1) and CH3 (1377 cm-1) absorptions and less intense aromatic C=C (1560-1610 cm-1) absorptions. The major products from analytical pyrolysis are cadalene based bicyclic sesquiterpenoids including some bicadinenes and bicadinanes. The polycadinane products confirm the fossil material as an Angiosperm dammar resin, associated with inputs of tropical rain forests supported by past climates.Keywords
Fossil Resin, Eocene, Polycadalene, Cambay Basin, Western India.References
- ALAM, M. and PEARSON, M.J. (1993) Bicadinanes and other terrestrial terpenoids in immature Oligocene sedimentary rocks and a related oil from the Surma Basin, N.E. Bangladesh. Org. Geochem., v.20(5), pp.539-554.
- ALIMOHAMMADIAN, H., SAHNI, A., PATNAIK, R., RANA, R.S. and SINGH, H. (2005) First record of an exceptionally diverse and well preserved amber-embedded biota from Lower Eocene (∼ 52 Ma) lignites, Vastan, Gujarat. Curr. Sci., v.89(8), pp.1328- 1330.
- ANDERSON, K.B., WINANS, R.E. and BOTTO, R.E. (1992) The nature and fate of natural resins in the geosphere-II. Identification, classification and nomenclature of resinites. Org. Geochem., v.18(6), pp.829-841.
- ANTAL, J.S. and PRASAD, M. (1996) Dipterocarpaceous fossil leaves from Ghish River section in Himalayan foot-hills near Oodlabari, Darjeeling District, West Bengal. Paleobot., v.43(3), pp.73-77.
- CRELLING, J.C. and KRUGE, M.A. (1998) Petrographic and chemical properties of carboniferous resinite from the Herrin No. 6 coal seam. Int. Jour. of Coal Geol., v.37(3-4), pp.55-71.
- GARG, R., ATEEQUZZAMAN, K., SINGH, V., TRIPATHI, S.K.M., SINGH, I.B., JAUHRI, A. and BAJPAI, S. (2008) Age-diagnostic dinoflagellate cysts from the lignite-bearing sediments of the Vastan Lignite Mine, Surat District, Gujarat, Western India. Jour. Paleont. Soc. India, v.53, pp.99-105.
- GOSWAMI, B.G., BISHT, R.S., BHATNAGAR, A.K., KUMAR D., PANGTEY, K.L., MITTAL, A.K., GOEL J.P., DATTA, G.C. and THOMAS, N.J. (2005) Geochemical characterization and source investigation of oils discovered in Khoraghat-Nambar structures of the Assam-Arakan Basin, India. Org. Geochem., v.36(2), pp.161-181.
- KRAEMER, M.M.S. and EVENHUIS, N.L. (2008) The first keroplatid (Diptera: Keroplatidae) species from the Lower Eocene amber of Vastan, Gujarat, India. Zootaxa, v.1816, pp.57-60.
- LAKHANPAL, R.N. and GULERIA, J.S. (1987) Fossil leaves of Dipterocarpus from the Lower Siwalik beds near Jawalamukhi, Himachal Pradesh. Palaeobot., v.35(3), pp.258-262.
- LANGENHEIM, J.H. (1969) Amber: a botanical inquiry. Science, v.163, pp.1157-1169.
- LANGENHEIM, J.H. (1990) Plant resins. Am. Scientist, v.78, pp.16-24.
- PAINTER, P.C., STARSINIC, M. and COLEMAN, M.M. (1985) Determination of functional groups in coal by Fourier Transform Interferometry. In: J.R. Ferraro and L.J. Basile (Eds.), Fourier Transform Infrared Spectroscopy. v.4, Academic Press, New York, pp.169-240.
- PANDE, A., UNIYAL, A.K. and CHANDRA, K. (1994) Genetic correlation of biodegraded crude oils from Lower Assam, India using biomarker compositions. Org. Geochem., v.21(8/9), pp.971-977.
- PRASAD, M. and PRAKASH, U. (1987) Occurrence of Malayan dipterocarps in the Siwalik sediments of Uttar Pradesh. Geophytology, v.17(2), pp.245-55.
- SAHNI, A., SARASWATI, P.K., RANA, R.S., KUMAR, K., SINGH, H., ALIMOHAMMADIAN, H., SAHNI, N., ROSE, K.D., SINGH, L. and SMITH, T. (2006) Temporal constraints and depositional paleoenvironments of the Vastan Lignite Sequence, Gujarat: Analogy for the Cambay Shale Hydrocarbon Source Rock. Indian Jour. Petroleum Geol., v.15, pp.1-20.
- SAHNI, N., SINGH, M. P., BAJPAI, U., AGARWAL, A., ALIMOHAMMADIAN, H. and SARKAR, N. (2007) Ultrastructure of a Lower Eocene leaf surface impression in amber, Vastan Lignite Mine, Gujarat. Jour. Paleont. Soc. India, v.52(1), pp.69-73.
- STOUT, S.A. (1995) Resin-Derived Hydrocarbons in Fresh and Fossil Dammar Resins and Miocene Rocks and Oils in the Mahakam Delta, Indonesia. In: K.B. Anderson and J.C. Crelling (Eds.), Amber, Resinite, and Fossil Resins. ACS Symposium Series 617, pp.43-75.
- VAN AARSSEN, B.G.K., COX, H.C., HOOGENDOORN, P. and DE LEEUW, J.W. (1990) A cadinene biopolymer in fossil and extant dammar resins as a source for cadinanes and bicadinanes in crude oils from South East Asia. Geochim. Cosmochim. Acta, v.54(11), pp.3021-3031.
- VAN AARSSEN, B.G.K., DE LEEUW, J.W. and HORSFIELD, B. (1991) A comparative study of three different pyrolysis methods used to characterise a biopolymer isolated from fossil and extant dammar resins. Jour. of Anal. and Appl. Pyrolysis, v.20, pp.125-139.
- VAN AARSSEN, B.G.K., DE LEEUW, J.W., COLLINSON, M., BOON, J.J. and GOTH, K. (1994) Occurrence of polycadinene in fossil and recent resins. Geochim. Cosmochim. Acta, v.58(1), pp.223-229.
- Preserved Lignin Structures in Early Eocene Surat Lignites, Cambay Basin, Western India
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Authors
Affiliations
1 Department of Earth Sciences, Indian Institute of Technology Bombay, Powai, Mumbai-400076, IN
2 Forschungzentrum Juelich, Institut fuer Chemie und Dynamik der Geosphaere, D-52425 Juelich, DE
1 Department of Earth Sciences, Indian Institute of Technology Bombay, Powai, Mumbai-400076, IN
2 Forschungzentrum Juelich, Institut fuer Chemie und Dynamik der Geosphaere, D-52425 Juelich, DE
Source
Journal of Geological Society of India (Online archive from Vol 1 to Vol 78), Vol 79, No 4 (2012), Pagination: 345-352Abstract
Lignite samples from Vastan and Tadkeshwar lignite mines, Cambay Basin have been analysed to elucidate lignin precursor using thermochemolysis-gas chromatography-mass spectrometry. The thermochemolysis products of lignites are characterized by monomethoxy-, dimethoxy-, and trimethoxybenzene derivatives originated from p-hydroxyphenyl, guaiacyl, and syringyl units of lignin polymer, respectively. The other compounds obtained in thermochemolysates of studied lignites are some resin derived C15 sesquiterpenoids, with a series of fatty acid methyl esters and n-alkanes/alkenes. The methylated guaiacyl and syringyl derivatives originate from the cleavage of β - O - 4 linkages and subsequent methylation of acidic hydroxyl groups of preserved lignin. Gymnosperm lignin is characterized mainly by guaiacyl derivatives whereas angiosperm lignin yields some syringyl-type compounds in addition to guaiacyl-type compounds. By analogy with the lignin structure of modern trees, the abundant occurrences of syringyl derivatives in the thermochemolysis products of Surat lignites clearly demonstrate that the palaeofloral community was dominated by angiosperms during the deposition of these lignites.Keywords
Lignite, Lignin, Early Eocene, Cambay Basin.References
- AMIJAYA, H. and LITTKE, R. (2006) Properties of thermally metamorphosed coal from Tanjung Enim Area, South Sumatra Basin, Indonesia with special reference to the coalification path of macerals. Internat. Jour. Coal Geol., v.66, pp.271-295.
- BATES, A.N. and HATCHER, P.G. (1989) Solid-state 13C NMR studies of a large fossil gymnosperm from the Yallourn Open Cut, Latrobe Valley, Australia. Organic Geochemistry, v.14, pp.609-614.
- BEHAR, F. and VANDENBROUCKE, M. (1987) Chemical modelling of kerogens. Organic Geochemistry, v.11, pp.15-24.
- BOTTO, R.E. (1987) Solid 13C NMR tracer studies to probe coalification. Energy Fuels, v.1, pp.228-230
- CHALLINOR, J.M. (1995) Characterization of wood by pyrolysis derivatization-gas chromatography/mass spectrometry. Jour. Analytical and Applied Pyrolysis, v.35, pp.93-107.
- CLIFFORD, D.J., CARSON, D.M., MCKINNEY, D.E., BORTIATYNSKI, J.M. and HATCHER, P.G. (1995) A new rapid technique for the characterization of lignin in vascular plants: thermochemolysis with tetramethylammonium hydroxide (TMAH). Organic Geochemistry, v.23, pp.169-175.
- COLLINSON, M.E., VAN BERGAN, P.F., SCOTT, A.C. and DE LEEUW, J.W. (1994) The oil-generating potential of plants from coal and coal-bearing strata through time: a review with new evidence from Carboniferous plants. In: A.C. Scott and A.J. Fleet (Eds.), Coal and Coal-bearing Strata as Oil-Prone Source Rocks? Geol. Soc. Spec. Publ., no.77, pp.31-70.
- COOPER, J.E. and BRAY, E.E. (1963) A postulated role of fatty acids in petroleum formation. Geochim. Cosmochim. Acta, v.27, pp.1113-1127.
- DE LEEUW, J.W. and LARGUEU, C. (1993) A review of macromolecular organic compounds that comprise living organism and their role in kerogen, coal and petroleum formation. In: M.H. Engel and S.A. Macko (Eds.), Organic Geochemistry. Plenum Publishing Corporation, New York. p.23.
- DUTTA, S. (2006) Biomacromolecules of fossil algae, spores, and zooclasts from selected time windows of Proterozoic to Mesozoic age as revealed by pyrolysis-gas chromatography mass-spectrometry: A biogeochemical study. ISBN: 3-89336-455-2. 138 p.
- DUTTA, S., MALLICK, M., BERTRAM, N., GREENWOOD, P.F. and MATHEWS, R.P. (2009) Terpenoid composition and class of Tertiary resins from India. Internat. Jour. Coal Geol., v.80, pp.44-50.
- GARG, R., ATEEQUZZAMAN, K., PRASAD, V., TRIPATHI, S.K.M., SINGH, I.B., JAUHRI, A.K. and BAJPAI, S. (2008) Age-diagnostic dinoflagellate cysts from the lignite-bearing sediments of the Vastan lignite mine, Surat District, Gujarat, Western India. Jour. Palaeont. Soc. India, v.53, pp.99-105.
- HATCHER, P.G. and CLIFFORD, D.J. (1997) The organic geochemistry of coal: from plant materials to coal. Organic Geochemistry, v.23, pp.169-175.
- HATCHER, P.G., LERCH, H.E. and VERHEYEN, T.V. (1989a) Organic Geochemical studies of the transformation of gymnospermous xylem during peatification and coalification to subbituminous coal. Internat. Jour. Coal Geol., v.13, pp.65-97.
- HATCHER, P.G., WILSON, M.A., VASSALLO, A.M. and LERCH, H.E. (1989b) Studies of angiospermous wood in Australian brown coal by nuclear magnetic resonance and analytical pyrolysis: new insights into the early coalification process. Internat. Jour. Coal Geol., v.13, pp.99-126.
- IBARRA, J.V., MUÑOZ, E. and MOLINER, R. (1996) FTIR study of the evolution of coal structure during the coalification process. Organic Geochemistry, v.24, pp.725-735.
- LAFARGUE, E., MARQUIS, F. and PILLOT, D. (1998) Rock-Eval 6 applications in hydrocarbon exploration, production and soil contamination studies. Oil & Gas Sci. Tech., v.53, pp.421-437.
- MALLICK, M., DUTTA, S., GREENWOOD, P.F. and BERTRAM, N. (2009) Pyrolytic and Spectroscopic Studies of Eocene Resin from Vastan Lignite Mine, Cambay Basin, Western India. Jour. Geol. Soc. India, v.74, pp.16-22.
- MANDAL, J. and GULERIA, J.S. (2006) Palynology of Vastan lignite (Surat District), Gujarat: its age, palaeoecology and depositional environment. Palaeobotanist, v.55, pp.51-66.
- MARTIN, F., RIO DEL, J.C., GONZALEZ-VILLA, F.J. and VERDEJO, T. (1995) Thermally assisted hydrolysis and alkylation of lignins in the presence of tetra-alkylammonium hydroxides. Jour. Analytical and Applied Pyrolysis, v.35, pp.1-13.
- MCKINNEY, D.E. and HATCHER, P.G. (1995) Characterization of peatified and coalified wood by tetramethylammonium hydroxide (TMAH) thermochemolysis. Internat. Jour. Coal Geol., v.32, pp.217-228.
- MILLAR, A.A., SMITH, M.A. and KUNST, L. (2000) All fatty acids are not equal: discrimination in plant membrane lipids. Trends in Plant Science, v.5, pp.95-101.
- MONGENOT, A., RIBOULLEAU, A., GARCETTE-LEPECQ, A., DERENNE, S., POUET, Y., BAUDIN, F. and LARGEAU, C. (2001) Occurrence of proteinaceous moieties in S- and O-rich late Tithonian kerogen (Kashpir Oil Shales, Russia). Organic Geochemistry, v.32, pp.199-203.
- MORRISON, W.H. III and MULDER, M.M. (1994) Pyrolysis mass spectrometry and pyrolysis gas chromatography-mass spectrometry of ester-and-ether-linked phenolic acids in coastal bermudagrass cell walls. Phytochemistry, v.35, pp.1143-1151.
- MULDER, M.M., VAN DER HAGE, E.R.E. and BOON, J.J. (1992) Analytical in source Pyrolytic methylation electron impact mass spectrometry of phenolic acids in biological matrices. Phytochemical Analysis, v.3, pp.156-172.
- OREM, W.H., NEUZIL, S.G., LERCH, H.E. and CECIL, C.B. (1996) Experimental early-stage coalification of a peat sample and a peatified wood sample from Indonesia. Organic Geochemistry, v.24, pp.111-125.
- PETERSEN, H.I., ROSENBERG, P. and NYTOFT, H.P. (2008) Oxygen groups in coals and alginite-rich kerogen revisited. Internat. Jour. Coal Geol., v.74, pp.93-113.
- PUNEKAR, J. and SARASWATI, P.K. (2010) Age of the Vastan lignite in context of some oldest Cenozoic fossil mammals from India. Jour. Geol. Soc. India, v.76, pp.63-68.
- SAHNI, A., SARASWATI, P.K., RANA, R.S., KUMAR, K., SINGH, H., ALIMOHAMMADIAN, H., SAHNI, N., ROSE, K.D., SINGH, L. and SMITH, T. (2006) Temporal Constraints and Depositional Palaeoenvironments of the Vastan Lignite Sequence, Gujarat: Analogy for the Cambay Shale hydrocarbon source rock. Indian Jour. Petroleum Geol., v.15, pp.1-20.
- STIHOLE, B.B. (2000) Applications of analytical pyrolysis in the pulp and paper industry. In: R.A. Meyers (Ed.), Encyclopedia of Analytical Chemistry: Applications, Theory and Instrumentation v.10, pp. 8443-8481. John Wiley & Sons, New York.
- STOUT, S.A., BOON, J.J. and SPACKMAN, W. (1988) Molecular aspects of the peatification and early coalification of angiosperm and gymnosperm woods. Geochim. Cosmochim. Acta, v.52, pp.405-415.
- VENKATESAN, M.I., OHTA, K., STOUT, S.A., STEINBERG, S. and OUDIN, J.L. (1993) Diagenetic trends of lignin phenols in Mahakam Delta coals: Correlation between laboratory simulation and natural samples. Organic Geochemistry, v.20, pp.463-473.